Hypervalent iodine oxidation of trimethylsilyl enol ethers of ketones: A direct synthesis of α-keto triflates

Authors :: Alok K. Awasthi
W. Ruwan Epa
Raju Penmasta
Robert M. Moriarty
Source :: Tetrahedron Letters. 30:667-670
Publication Year :: 1989
Publisher :: Elsevier BV, 1989.
Abstract: α-Trifluoromethanesulfonoxy ketones (α-keto triflates) have been synthesized under very mild conditions by the reaction of silyl enol ethers of ketones and trimethylsily trifluormethanesulfonate/iodosobenzene in dichloromethane.

Subjects :: Iodosobenzene
Trimethylsilyl
Silylation
Organic Chemistry
Hypervalent molecule
chemistry.chemical_element
Iodine
Biochemistry
Enol
chemistry.chemical_compound
chemistry
Drug Discovery
Organic chemistry
Dichloromethane

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