Reversibility of .eta.4-cyclobutadiene metal formation from complexed alkynes: unimolecular isomerization of labeled racemic and enantiomerically enriched .eta.5-cyclopentadienyl-.eta.4-cyclobutadiene-cobalt complexes

Authors :: G. Ville
Mark J. Winter
K. Peter C. Vollhardt
Source :: Journal of the American Chemical Society. 103:5267-5269
Publication Year :: 1981
Publisher :: American Chemical Society (ACS), 1981.
Abstract: Evidence is presented for the reversible formation of metal-alkyne complex in the pyrolysis of eta/sup 5/-cyclopentadienyl-eta/sup 4/-cyclobutadiene-cobalt complexes. (DLC)

Subjects :: Cyclopentadiene
chemistry.chemical_element
General Chemistry
Photochemistry
Biochemistry
Medicinal chemistry
Chemical reaction
Catalysis
Metal
chemistry.chemical_compound
Colloid and Surface Chemistry
chemistry
Cyclopentadienyl complex
visual_art
visual_art.visual_art_medium
Cyclobutadiene
Cobalt
Isomerization
Pyrolysis

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