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Synthesis and characterization of [RuCl2(picoline)4] complexes: Crystal structure of [RuCl2(β-pic)4]

Authors :
Maria Jaworska
R. Gil-bortnowska
Rafal Kruszynski
Jan Grzegorz Małecki
Source :
Polyhedron. 24:1445-1453
Publication Year :
2005
Publisher :
Elsevier BV, 2005.

Abstract

The reaction of the [RuCl2(PPh3)3] complex with picolines has been examined. New ruthenium(II) complexes – [RuCl2(C6H7N)4] have been obtained and characterized by IR, 1H NMR and UV–Vis measurements. The crystal structure of the [RuCl2(β-pic)4] complex has been determined. The electronic spectra of the complexes have been calculated by the TDDFT method.

Details

ISSN :
02775387
Volume :
24
Database :
OpenAIRE
Journal :
Polyhedron
Accession number :
edsair.doi...........1d97fc10457e8c461b46a446188baab7
Full Text :
https://doi.org/10.1016/j.poly.2005.03.092