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HIGHLY EFFICIENT SYNTHESIS OF 2-AMINO-3-PYRIDINECARBOXALDEHYDE

Authors :
Jennifer A. Cowen
Christopher McWilliams
Yi Hsiao
J. D. Armstrong
Nelo R. Rivera
Nobuyoshi Yasuda
David L. Hughes
Source :
Synthetic Communications. 31:1573-1579
Publication Year :
2001
Publisher :
Informa UK Limited, 2001.

Abstract

2-Amino-3-pyridinecarboxaldehyde is synthesized in a highly efficient process via ortho-lithiation of 2-(pivaloylamino)pyridine and reaction with DMF, followed by acid hydrolysis. Major impurities were identified and were cleanly eliminated through careful choice of base and solvent.

Details

ISSN :
15322432 and 00397911
Volume :
31
Database :
OpenAIRE
Journal :
Synthetic Communications
Accession number :
edsair.doi...........1dd8c006cc213045f8e92f22ba22c0b0