Isomerization in the 1,4,7,10,13,16-Hexaazacyclooctadecanecobalt(III) System [Co(hexacyclen)]3+, and Ion-Association Enhancement of the Unstable Facial Isomer

Authors :: Graeme H. Searle
Source :: Bulletin of the Chemical Society of Japan. 62:4021-4032
Publication Year :: 1989
Publisher :: The Chemical Society of Japan, 1989.
Abstract: The substitution reaction [Co(NH3)5(H2O)]3++hexacyclen·3H2SO4+6base+charcoal gives mer-[Co(hexacyclen)]3+ as the major product, and the equilibrium proportion of the fac isomer is

Subjects :: Substitution reaction
Elimination reaction
Hydrolysis
Reaction mechanism
Stereochemistry
Chemistry
Kinetics
General Chemistry
Chemical equilibrium
Ion-association
Medicinal chemistry
Isomerization

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