Lead distribution and possible sources along vertical zone spectrum of typical ecosystems in the Gongga Mountain, eastern Tibetan Plateau

A total of 383 samples from soil, plant, litterfall and precipitation in four typical ecosystems of Gongga Mountain were collected. Pb concentrations of samples were measured and analyzed. The results showed mean Pb concentrations in different soil layers were in the order of O > A > C, and mean Pb concentrations of the aboveground parts of plant was 3.60 +/- 2.54 mg kg(-1), with the minimum value of 0.77 mg kg(-1) and the maximum value of 10.90 mg kg(-1). Pb concentrations in soil's O-horizon and A-horizon showed a downward trend with increasing elevation (the determination coefficient R-2 was 0.9478, 0.7918 and 0.9759 respectively). In contrast to other soil layers, the level of Pb concentrations in O-horizon (incomplete decomposition) was significantly high. Litterfall decomposition, atmospheric deposition and the unique climate could be main factors leading high Pb accumulation in soil's O-horizon. What's more, significant correlation (R-2 = 0.8126, P < 0.05) was found between Pb concentrations in fine roots and soil's A-horizon confirms that fine roots could adsorb and accumulate Pb materials in soil. In general, the fact that Pb inputted into the typical ecosystems in the Gongga Mountain via long-range transportation and deposition of the atmosphere from external Pb sources could be confirmed by the HYSPLIT model and the ratio of C-Pb/C-Al in plants (leaves) and C-Pb/C-Al in litterfall. The mining activities and increasing anthropogenic activities (tourism development) could be main sources of Pb in this area. In order to better understand Pb sources and eco-risks of these typical ecosystems, litterfall decomposition characteristics, biomass of productivity of forest ecosystem, Pb isotopic tracing among air mass, twigs, leaves, litterfall and O-horizon soil in this vertical belt should also be taken into consideration. (C) 2015 Elsevier Ltd. All rights reserved.