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Controlling Plasmon-Induced Resonance Energy Transfer and Hot Electron Injection Processes in Metal@TiO2 Core–Shell Nanoparticles
- Source :
- The Journal of Physical Chemistry C. 119:16239-16244
- Publication Year :
- 2015
- Publisher :
- American Chemical Society (ACS), 2015.
-
Abstract
- Plasmonic metals can excite charge carriers in semiconductors through plasmon-induced resonance energy transfer (PIRET) and hot electron injection processes. Transient absorption spectroscopy reveals that the presence of plasmon-induced charge separation mechanisms in metal@TiO2 core–shell nanoparticles can be controlled by tailoring the spectral overlap and the physical contact between the metal and the semiconductor. In Ag@SiO2@TiO2 sandwich nanoparticles, the localized surface plasmon resonance band is overlapped with the absorption band edge of TiO2, enabling PIRET, while the SiO2 barrier prevents hot electron transfer. In Au@TiO2, hot electron injection occurs, but the lack of spectral overlap disables PIRET. In Ag@TiO2, both hot electron transfer and PIRET take place. In Au@SiO2@TiO2, photoconversion in TiO2 is not enhanced by the plasmon despite strong light absorption by Au.
- Subjects :
- Chemistry
business.industry
Physics::Optics
Resonance
Nanoparticle
Molecular physics
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Condensed Matter::Materials Science
General Energy
Semiconductor
Absorption band
Physics::Atomic and Molecular Clusters
Charge carrier
Physical and Theoretical Chemistry
Surface plasmon resonance
Atomic physics
business
Plasmon
Hot-carrier injection
Subjects
Details
- ISSN :
- 19327455 and 19327447
- Volume :
- 119
- Database :
- OpenAIRE
- Journal :
- The Journal of Physical Chemistry C
- Accession number :
- edsair.doi...........21da8865ea96e5d89dc6789eb10db754