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Protonation Reactions of [MH(Cl)(PPh3)2(norbornadiene)] (M = Ru, Os)

Authors :
Zhitao Xu
Sheng-Yong Yang
Ting-Bin Wen
Weng Sang Ng
Sheng Hua Liu
Chak Po Lau
Zhong Yuan Zhou
Shu Tak Lo
Guochen Jia
Zhenyang Lin
Source :
Organometallics. 20:4161-4169
Publication Year :
2001
Publisher :
American Chemical Society (ACS), 2001.

Abstract

Protonation of [RuH(Cl)(PPh3)2(NBD)] (NBD = norbornadiene) in benzene with a limiting amount of HOTf gives [RuH(OTf)(PPh3)2(NBD)], norbornene, and [RuCl2(PPh3)2]2. In dichloromethane, [RuH(Cl)(PPh3...

Subjects

Subjects :
Norbornadiene
Organic Chemistry
chemistry.chemical_element
Protonation
Crystal structure
Photochemistry
Medicinal chemistry
Ruthenium
Inorganic Chemistry
chemistry.chemical_compound
chemistry
Dihydrogen complex
Physical and Theoretical Chemistry
Benzene
Norbornene
Dichloromethane

Details

ISSN :
15206041 and 02767333
Volume :
20
Database :
OpenAIRE
Journal :
Organometallics
Accession number :
edsair.doi...........26ced95ee8b6054343bd90c0669763c1
Full Text :
https://doi.org/10.1021/om010029r
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