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NEW SYMMETRIC DIISOPROPYLPHOSPHORYL-S-ALKANEDI YLDIISOTHIOUREAS. INVESTIGATIONS ON THEIR SYNTHESIS
- Source :
- Phosphorus, Sulfur, and Silicon and the Related Elements. 148:143-148
- Publication Year :
- 1999
- Publisher :
- Informa UK Limited, 1999.
-
Abstract
- Symmetric dialkylphosphoryl-S-alkanediyldiisothiouas (RO)2P(O)NHC(=NH)S(CH2)n SC(=NH)NHP(O)(OR)2 (I, R = isopropyl; n = 2–5) have potential coordination sites involving O, P, N and S as donors atoms. For their synthesis, common two-phase reactions between the corresponding diisothiourea derivatives and diisopropyi phosphonate were unsuccessful. Herein we describe a new synthesis for such compounds using diisopropyl chlorophosphonate. Two new bis-phosphorylated alkanediyldiisothioureas with increasing carbon chain (I; n = 3, n = 5) were prepared by this method.
Details
- ISSN :
- 15635325 and 10426507
- Volume :
- 148
- Database :
- OpenAIRE
- Journal :
- Phosphorus, Sulfur, and Silicon and the Related Elements
- Accession number :
- edsair.doi...........26f3baebd8a052ab8d632fd3a9fffe2a