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Aglycon directed palladium β-alcoxyelimination on carbohydrate templates

Authors :
Laure Joseph
Véronique Bolitt
Karim Bedjeguelal
Denis Sinou
Source :
Tetrahedron Letters. 40:87-90
Publication Year :
1999
Publisher :
Elsevier BV, 1999.

Abstract

The palladium(0)-catalyzed Heck-type cyclisation reaction of erythro or threo aryl 2,3-unsaturated glycosides gave the enantiopure bicyclic compounds in quite good yields via a palladium β-alcoxyelimination.

Subjects

Subjects :
chemistry.chemical_classification
Bicyclic molecule
Stereochemistry
Aryl
Organic Chemistry
Diastereomer
Glycoside
chemistry.chemical_element
Carbohydrate
Biochemistry
chemistry.chemical_compound
Template
Enantiopure drug
chemistry
Drug Discovery
Organic chemistry
Palladium

Details

ISSN :
00404039
Volume :
40
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........28bcfc9fd0e1c6431d7391c50b6b0e77
Full Text :
https://doi.org/10.1016/s0040-4039(98)80026-9
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