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The critical role of ligand topology: strikingly different properties of Gd(<scp>iii</scp>) complexes with regioisomeric AAZTA derivatives
- Source :
- Inorganic Chemistry Frontiers. 9:2271-2283
- Publication Year :
- 2022
- Publisher :
- Royal Society of Chemistry (RSC), 2022.
-
Abstract
- Two regioisomeric Gd(III) complexes with heptadentate AAZTA-like ligands show different hydration state (q = 1 and 2) and astonishingly different thermodynamic stability and dissociation kinetics.
- Subjects :
- Inorganic Chemistry
Subjects
Details
- ISSN :
- 20521553
- Volume :
- 9
- Database :
- OpenAIRE
- Journal :
- Inorganic Chemistry Frontiers
- Accession number :
- edsair.doi...........2951d25887e8dd575677b26b6ef9eb38
- Full Text :
- https://doi.org/10.1039/d2qi00451h