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Three-Dimensional Supramolecular of 2-(γ-Aminopropyl)benzimidazole Dichloride Dihydrate via Various Hydrogen Bonds and X···π (X = π, CH) Interactions: Synthesis, Crystal Structure, Characterization, and Biochemical Property
- Source :
- Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry. 45:621-627
- Publication Year :
- 2014
- Publisher :
- Informa UK Limited, 2014.
-
Abstract
- The title compound, 2-(γ-aminopropyl)benzimidazole dichloride dihydrate ([H2APB2+][Cl−]2·2H2O), was synthesized and characterized by elemental analysis, IR, UV, 1H NMR, and fluorescent spectroscopic method. Single-crystal X-ray analysis was performed, which reveals that the benzimidazole and amine nitrogen atoms are protonated. The [H2APB2+] ions are linked into a 3D framework by chloride ions and two water molecules via hydrogen bonds, C‒H···π and π-π packing interactions between adjacent benzimidazole rings. Antibacterial activities of [H2APB2+][Cl−]2·2H2O have been studied on the strains S. aureus and E. coli.
Details
- ISSN :
- 15533182 and 15533174
- Volume :
- 45
- Database :
- OpenAIRE
- Journal :
- Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry
- Accession number :
- edsair.doi...........29cc1cde2e90ac2dc9f5284e762ea5e4