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Catalytic reduction of α-pinene using Ru nanoparticles stabilized by modified carboxymethyl cellulose
- Source :
- Applied Surface Science. 453:271-279
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- A new and environmental friendly route has been developed to hydrogenate α-pinene to cis-pinane. The α-pinene was hydrogenated using ruthenium (Ru) nanoparticles that were stabilized by modified carboxymethyl cellulose in aqueous medium. The conversion of α-pinene reached 96.6% and the selectivity of cis-pinane was 98.4%. Ru nanoparticles could be recycled 18 times. Ru nanoparticles and micelles were characterized by transmission electron microscopy (TEM), confocal laser scanning microscopy (CLSM), dynamic light scattering (DLS), X-ray diffraction (XRD), and other detection techniques. Ru nanoparticles (3.2 nm) had a good stability and uniform distribution, the reaction was divided into micelles that appeared to act as “microreactors”, and the micelle size was increased in the absence of sodium carbonate. The good stability of the Ru nanoparticles could be attributed to electrostatic and steric stabilization.
- Subjects :
- Materials science
010405 organic chemistry
General Physics and Astronomy
chemistry.chemical_element
Nanoparticle
Surfaces and Interfaces
General Chemistry
010402 general chemistry
Condensed Matter Physics
01 natural sciences
Micelle
0104 chemical sciences
Surfaces, Coatings and Films
Catalysis
Ruthenium
Carboxymethyl cellulose
chemistry
Dynamic light scattering
Transmission electron microscopy
medicine
Selectivity
medicine.drug
Nuclear chemistry
Subjects
Details
- ISSN :
- 01694332
- Volume :
- 453
- Database :
- OpenAIRE
- Journal :
- Applied Surface Science
- Accession number :
- edsair.doi...........2aff10b9f1ea61cf7323bdc4ed456f18