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Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O-CuIIInteraction
- Source :
- Zeitschrift für anorganische und allgemeine Chemie. 641:1744-1748
- Publication Year :
- 2015
- Publisher :
- Wiley, 2015.
-
Abstract
- Two uranyl complexes based on pyromellitic acid were hydrothermally synthesized, and their X-ray single-crystal diffraction structures were determined. Complex [UO2(Hbtec)]–(Himd)+·H2O (1) (H4btec = pyromellitic acid, imd = imidazole), is an ionic complex, which shows a typical (4, 4) topological structure in the space. A heterometallic complex, UO2Cu(btec)(phen) (2) (phen = 1,10-phenanthroline) results from the reaction of uranyl nitrate and copper(II) bromide with pyromellitic acid. The structure of complex 2 revealed that the chains of UO7 and CuO3N2 units were connected to each other through the carboxyl groups and U=O–Cu interactions to create a two-dimensional framework.
Details
- ISSN :
- 00442313
- Volume :
- 641
- Database :
- OpenAIRE
- Journal :
- Zeitschrift für anorganische und allgemeine Chemie
- Accession number :
- edsair.doi...........2b90e9a079c8946b888e28d671b52d64