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Atomic iron on mesoporous N-doped carbon to achieve dehydrogenation reaction at room temperature
- Source :
- Nano Research. 13:3075-3081
- Publication Year :
- 2020
- Publisher :
- Springer Science and Business Media LLC, 2020.
-
Abstract
- Atomic non-noble metal materials show the potential to substitute noble metals in catalysis. Herein, melamine formaldehyde resin is developed to synthesize atomic iron on mesoporous nitrogen-doped carbon. The triazine units with abundant nitrogen content and cavity can realize effectively anchoring of single metal atoms. The atomic iron with unique charge and coordination characteristics shows superior catalytic performance in dehydrogenation reaction. Various N-heterocycles compounds and amines can be efficiently dehydrogenated into the corresponding products at room temperature, which is the mildest of all reported reaction conditions even when noble metal catalysts are considered. Therefore, development of atomic non-noble metal catalysts with mesoporous structure may provide an effective way to realize the substitution for noble metals in heterogeneous catalysis.
- Subjects :
- Materials science
chemistry.chemical_element
02 engineering and technology
engineering.material
010402 general chemistry
Heterogeneous catalysis
01 natural sciences
Catalysis
Metal
chemistry.chemical_compound
General Materials Science
Dehydrogenation
Electrical and Electronic Engineering
Triazine
021001 nanoscience & nanotechnology
Condensed Matter Physics
Atomic and Molecular Physics, and Optics
0104 chemical sciences
Chemical engineering
chemistry
visual_art
engineering
visual_art.visual_art_medium
Noble metal
0210 nano-technology
Mesoporous material
Carbon
Subjects
Details
- ISSN :
- 19980000 and 19980124
- Volume :
- 13
- Database :
- OpenAIRE
- Journal :
- Nano Research
- Accession number :
- edsair.doi...........2c71ba70cb5abe13131794321aeb7af9