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ChemInform Abstract: New Chiral Allylaminosilanes and Their Use in Asymmetric Sakurai Reactions
- Source :
- ChemInform. 30
- Publication Year :
- 2010
- Publisher :
- Wiley, 2010.
-
Abstract
- The new allylaminosilanes 2a – c , derived from chiral amines, react with benzaldehyde and pivalaldehyde in the presence of SnCl 4 to give homoallylic alcohols 4a – b with enantiomeric excesses of up to 30%.
Details
- ISSN :
- 15222667 and 09317597
- Volume :
- 30
- Database :
- OpenAIRE
- Journal :
- ChemInform
- Accession number :
- edsair.doi...........2d149c6acdbf139fe394e3119a9ff849
- Full Text :
- https://doi.org/10.1002/chin.199910170