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Solid state 31P n.m.r. spectroscopy of surface-attached triosmium clusters

Authors :
Nigel J. Clayden
Christopher M. Dobson
Stephen L. Cook
Deborah J. Smith
Valentin D. Alexiev
John S. O. Evans
Source :
Journal of the Chemical Society, Chemical Communications. :938
Publication Year :
1986
Publisher :
Royal Society of Chemistry (RSC), 1986.

Abstract

Whilst the 31P n.m.r. spectra of H2Os3(CO)10L′ and Os3(CO)11L′{L′= PPh2[CH2]2Si(OEt)3} bound to silica are consistent with simple immobilisation, that of materials reported to contain H2Os3(CO)9L′ are inconsistent with this structure.

Details

ISSN :
00224936
Database :
OpenAIRE
Journal :
Journal of the Chemical Society, Chemical Communications
Accession number :
edsair.doi...........2f57f148afb073bcb099926052d8f67e
Full Text :
https://doi.org/10.1039/c39860000938