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Observation of an Excited Singlet Charge-Transfer Complex (or a Singlet Ion Pair) Produced by Excitation of a Ground-State Complex of 1,8-Dichloroanthraquinone with 2,5-Dimethylhexa-2,4-diene

Authors :
Hideyuki Sasaki
Kumao Hamanoue
Satoshi Asada
Toshihiro Nakayama
Source :
Chemistry Letters. 22:105-108
Publication Year :
1993
Publisher :
The Chemical Society of Japan, 1993.

Abstract

1,8-dichloroanthraquinone forms a weak ground-state complex with 2,5-dimethylhexa-2,4-diene, and its selective excitation by the picosecond 435-nm light pulse generates an excited singlet charge-transfer complex (or a singlet ion pair) with a lifetime of 100 ps.

Details

ISSN :
13480715 and 03667022
Volume :
22
Database :
OpenAIRE
Journal :
Chemistry Letters
Accession number :
edsair.doi...........2f63372595747345f987ac3de378daca