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Efficient destruction of sodium cyanide by thermal decomposition with addition of ferric oxide
- Source :
- Transactions of Nonferrous Metals Society of China. 31:1113-1126
- Publication Year :
- 2021
- Publisher :
- Elsevier BV, 2021.
-
Abstract
- Efficient destruction of cyanide by thermal decomposition with ferric oxide addition was proposed. The mechanism of destruction of sodium cyanide with or without ferric oxide addition under various conditions was examined by XRD, DSC−TG, and chemical analysis technologies. In the absence of ferric oxide, sodium cyanide decomposes at 587.4 °C in air and 879.2 °C in argon atmosphere. In the presence of ferric oxide, about 60% of sodium cyanide decomposes at 350 °C for 30 min in argon, while almost all sodium cyanide decomposes within 30 min in air or O2 with mass ratio of ferric oxide to sodium cyanide of 1:1. The increase of ferric oxide addition, temperature, and heating time facilitates the destruction of sodium cyanide. It is believed that with ferric oxide addition, NaCN reacts with Fe2O3 to form Na4Fe(CN)6, Na2CO3, NaNO2 and Fe3O4 in argon. NaCN decomposes into NaCNO, Na4Fe(CN)6, minor NaNO2, and the formed NaCNO and Na4Fe(CN)6 further decompose into Na2CO3, CO2, N2, FeOx, and minor NOx in air or O2.
- Subjects :
- inorganic chemicals
010302 applied physics
Argon
Cyanide
Thermal decomposition
Inorganic chemistry
Metals and Alloys
Oxide
chemistry.chemical_element
02 engineering and technology
021001 nanoscience & nanotechnology
Geotechnical Engineering and Engineering Geology
Condensed Matter Physics
01 natural sciences
chemistry.chemical_compound
chemistry
0103 physical sciences
Materials Chemistry
medicine
Ferric
0210 nano-technology
NOx
Argon atmosphere
Sodium cyanide
medicine.drug
Subjects
Details
- ISSN :
- 10036326
- Volume :
- 31
- Database :
- OpenAIRE
- Journal :
- Transactions of Nonferrous Metals Society of China
- Accession number :
- edsair.doi...........30431a879714787f6a7cbb3721505512
- Full Text :
- https://doi.org/10.1016/s1003-6326(21)65565-6