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The chiral oxime of 13H-dibenzo(a,i)fluoren-13-one

Authors :
David G. Morris
Karl S. Ryder
Sean Higgins
Kenneth W. Muir
Source :
Canadian Journal of Chemistry. 82:1625-1628
Publication Year :
2004
Publisher :
Canadian Science Publishing, 2004.

Abstract

On the basis of single crystal diffraction analyses it is shown that conversion of 13H-dibenzo(a,i)fluoren-13-one into its oxime causes distortion of the aromatic framework because of steric crowding. The oxime is, in consequence, chiral.Key words: oxime, crystal structure, chirality.

Details

ISSN :
14803291 and 00084042
Volume :
82
Database :
OpenAIRE
Journal :
Canadian Journal of Chemistry
Accession number :
edsair.doi...........30dd57b4f42bb4071b578b9267d5dfaa
Full Text :
https://doi.org/10.1139/v04-133