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Synergistic band modulation and precipitates: Achieving high quality factor in SnTe
- Source :
- Applied Physics Letters. 122:072102
- Publication Year :
- 2023
- Publisher :
- AIP Publishing, 2023.
-
Abstract
- Breaking the thermoelectric figure of merit zT barrier of SnTe enables it to become a promising alternative to PbTe; however, the inferior and strongly coupled physicochemical properties of pristine SnTe severely restrict the efficient optimization. Herein, we doped trivalent Sb in SnTe and incorporated SnS particles to achieve high quality factor B through a two-step optimization strategy of tuning the valence band structure and intercalating heterostructural precipitates, and well predicted the potential prospects. The high solubility limit of Sb not only reduced the carrier concentration nH but also significantly optimized the valence band structure and improved the Seebeck coefficient, thereby enhancing the weight mobility μw in the all-temperature region. Furthermore, the additional SnS, which tends to exist as precipitates with different micrometer-scale sizes, enhanced low-medium-frequency phonon scattering in a wider frequency range except for point defects scattering, suppressing the lattice thermal conductivity to 0.55 W m−1 K−1. As a result of this synergistic effect, a high B-factor of ∼0.82 greater than triple pure SnTe was obtained in Sn0.91Sb0.09Te-10%SnS, with an enhanced zT of ∼1.15 at 850 K. More importantly, the high B-factor accurately predicted an excellent zT value of ∼1.65 at the optimal Fermi level, which highlights the great potential of Sn1- xSb xTe- y%SnS-based materials. This work provides an effective route for stepwise optimization of electrical and thermal performance from the B-factor perspective and has guiding significance for other thermoelectric materials.
- Subjects :
- Physics and Astronomy (miscellaneous)
Subjects
Details
- ISSN :
- 10773118 and 00036951
- Volume :
- 122
- Database :
- OpenAIRE
- Journal :
- Applied Physics Letters
- Accession number :
- edsair.doi...........3190410d62923ec0cf225686fcba4790