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C(sp3)–H bond activation by the carboxylate-adduct of osmium tetroxide (OsO4)

Authors :
Tomohiro Fujimoto
Yuka Hirata
Hideki Sugimoto
Mayuko Miyanishi
Yoshihito Shiota
Kazunari Yoshizawa
Shinobu Itoh
Source :
Dalton Transactions. 51:1123-1130
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

The carboxylate adducts of OsO4 ([OsO4(X)]−, X− = AcO− and BzO−) were isolated and their structures, physicochemical properties and reactivity were explored. The C(sp3)−H oxygenation mechanism by the carboxylate adducts was discussed based on their kinetics and DFT studies.

Details

ISSN :
14779234 and 14779226
Volume :
51
Database :
OpenAIRE
Journal :
Dalton Transactions
Accession number :
edsair.doi...........32656fbe2b38fc2e2c7db717bfdc8694
Full Text :
https://doi.org/10.1039/d1dt03819b