[Untitled]

Authors :: Yu. E. Gorbunova
L. A. Zemnukhova
Anatoly A. Udovenko
Ruven L. Davidovich
Yu. N. Mikhailov
Source :: Russian Journal of Coordination Chemistry. 29:310-311
Publication Year :: 2003
Publisher :: Springer Science and Business Media LLC, 2003.
Abstract: The crystal structure of thallium fluoroantimonate(III) complex TlSb4F13 (I), which is isostructural to KSb4F13 (II), is determined. Crystals I are tetragonal: a = 9.634(2) A, c = 6.590(2) A, V = 611.7(2) A3, Z = 2, ρ(calcd) = 5.094 g/cm3, F(000) = 804.0, space group I4¯. The structure consists of tetrameric [Sb4F13]– anions formed by SbF3 groups connected by the fluoride ion and the Тl+ cations.