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On the in situ trimethylsilylation of zinc acetylides

Authors :
Säde Viirlaid
Hannes Hagu
Uno Mäeorg
Hermann D. Verkruijsse
Lambert Brandsma
Source :
Journal of Organometallic Chemistry. 601:341-342
Publication Year :
2000
Publisher :
Elsevier BV, 2000.

Abstract

Reinvestigation of the recently published formation of silylated alkynes by reaction of 1-alkynes with zinc and trimethylchlorosilane in acetonitrile showed that appreciable amounts of 1-alkenes are formed as side products.

Subjects

Subjects :
Inorganic Chemistry
In situ
chemistry.chemical_compound
Silylation
Chemistry
Organic Chemistry
Inorganic chemistry
Materials Chemistry
chemistry.chemical_element
Zinc
Physical and Theoretical Chemistry
Acetonitrile
Biochemistry

Details

ISSN :
0022328X
Volume :
601
Database :
OpenAIRE
Journal :
Journal of Organometallic Chemistry
Accession number :
edsair.doi...........3592c29cd5bf16380011c71f57132249

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