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Compounds Featuring the Structural Fragment P-C-P
- Source :
- Phosphorus, Sulfur, and Silicon and the Related Elements. 186:621-625
- Publication Year :
- 2011
- Publisher :
- Informa UK Limited, 2011.
-
Abstract
- This article summarizes some of our investigations of compounds featuring the structural fragment P‒C‒P. Phosphorus atoms in different oxidation states and coordination numbers display different chemical behaviors. This may lead to unique chemical properties when they are bridged by a methylene group in a P‒CH2‒P system. For example, the PIII‒CH2‒PVunit is able to add different unsaturated compounds to give zwitterionic products with oppositely charged phosphorus atoms. In addition, the two hydrogen atoms in P‒CH2‒P may also take part in different transformations, resulting in the formation of carbodiphosphoranes or in the formation of a direct P-P bond to give three-membered ring diphosphiranes.
Details
- ISSN :
- 15635325 and 10426507
- Volume :
- 186
- Database :
- OpenAIRE
- Journal :
- Phosphorus, Sulfur, and Silicon and the Related Elements
- Accession number :
- edsair.doi...........3666bb04e0deb8b52f92a2effc624533
- Full Text :
- https://doi.org/10.1080/10426507.2010.520285