Electrochemical behaviour and structural characterization of highly crystalline poly(p-phenylene) films obtained by oxidation of benzene in a concentrated sulfuric acid emulsion

Authors :: Elena B. Molodkina
E. Yu. Pisarevskaya
A. I. Danilov
Mikhael D. Levi
Source :: Synthetic Metals. 54:195-201
Publication Year :: 1993
Publisher :: Elsevier BV, 1993.
Abstract: Poly( p -phenylene) (PPP) films deposited from benzene in concentrated H 2 SO 4 emulsion reveal a highly crystalline structure under TEM, SEM and XDA in contrast to nearly completely amorphous films deposited from C 6 H 5 NO 2 medium. Possible effects of solvent and electrolyte specificity on the morphology and mechanical properties of PPP films are discussed in view of these results.

Subjects :: Materials science
Mechanical Engineering
Inorganic chemistry
Metals and Alloys
Sulfuric acid
Condensed Matter Physics
Electrochemistry
Electronic, Optical and Magnetic Materials
Amorphous solid
Solvent
chemistry.chemical_compound
chemistry
Chemical engineering
Mechanics of Materials
Phenylene
Poly(p-phenylene)
Emulsion
Materials Chemistry
Benzene

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