Synthesis and molecular structure of nickel-antimony alkoxide, Ni5Sb3O2(OEt)15(HOEt)4

Authors :: Gunnar Westin
Rolf Norrestam
U. Bemm
Mats Nygren
Source :: Inorganic Chemistry. 31:2050-2053
Publication Year :: 1992
Publisher :: American Chemical Society (ACS), 1992.
Abstract: A new Ni-Sb alkoxide of the formula Ni 5 Sb 3 O 2 (OEt) 15 (HOEt) 4 has been prepared by reacting anhydrous NiCl 2 with NaSb(OEt) 4 and NaOEt in a toluene/ethanol solution in dry, oxygen-free atmosphere. Ni 5 Sb 3 O 2 (OEt) 15 (HOEt) 4 crystallizes in the noncentrosymmetric space group Pca2 l , with a=17.909 (2) A,b=20.608 (3) A,c=17.221 (2) A,V=6356 (1) A 3 , Z=4,D x =1.621 (4) g/cm 3 , and fw=1550.89

Subjects :: Stereochemistry
chemistry.chemical_element
Crystal structure
Toluene
Inorganic Chemistry
chemistry.chemical_compound
Nickel
chemistry
Antimony
Alkoxide
X-ray crystallography
Anhydrous
Molecule
Physical and Theoretical Chemistry
Nuclear chemistry

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