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Effects of Li pre-doping on charge/discharge properties of Si thin flakes as a negative electrode for Li-ion batteries
- Source :
- Solid State Ionics. 262:39-42
- Publication Year :
- 2014
- Publisher :
- Elsevier BV, 2014.
-
Abstract
- To compensate the large irreversible capacity (Qirr), lithium was pre-doped to Si thin flakes (Si Leaf Powder® (Si-LP), thickness: 100 nm) for different times, and its effects on the charge/discharge characteristics such as reversible capacity, cycleability, and rate-capability were investigated in detail. The charge/discharge test results showed that a large initial Qirr of ca. 2300 mAh g− 1 for the Si-LP can be completely compensated by Li pre-doping, and a high capacity (> 2500 mAh g− 1) was obtained for pre-doped Si-LPs. The pre-doping did not cause any harmful effects on cycleability as long as lithium was uniformly pre-doped. The addition of vinylene carbonate to the electrolyte solution in the pre-doping and in the test cell greatly improved the cycleability, and a high discharge capacity of ca. 2300 mAh g− 1 was kept after 40 cycles.
Details
- ISSN :
- 01672738
- Volume :
- 262
- Database :
- OpenAIRE
- Journal :
- Solid State Ionics
- Accession number :
- edsair.doi...........370d5931863c52752d518eaa7a0347f1
- Full Text :
- https://doi.org/10.1016/j.ssi.2013.09.014