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Studies of the In-Situ Epoxidation of Rubber (Hevea Brasiliensis)Seed Oil by Performic Acid

Authors :
O. J. Omodara
Babalola Aisosa Oni
O. R. Obanla
Modupe Elizabeth Ojewumi
Olayinka O. Ajani
Joseph Denis Udonne
Source :
Journal of Physics: Conference Series. 1378:022025
Publication Year :
2019
Publisher :
IOP Publishing, 2019.

Abstract

Studies on the epoxidation of rubber (Hevea brasiliensis) seed oil, a renewable source with formic acid was performed in the presence of 30% hydrogen peroxide at a of temperature 40, 50, 60, 70 °C. The process is favoured by an increase in temperature forming a product with high oxirane content which is as a result of mole ratios of formic acid and hydrogen peroxide. Products of high oxirane content are commercialy viable in the production of polyvinyl chloride (PVC). Natural rubber and other products can be obtained from this in- situ technique. Studies in this research shows that the rate of epoxidation increases with an increase in temperature.Oxirane values of 2.30, 3.62 and 4.73 for the various temperature. However high oxirane content of 6.22 was obtained at 70 °C which is in line with literature. FTIR analysis was also carried out on the epoxidized rubber seed oil which shows the peaks of oxirane cleavage.

Details

ISSN :
17426596 and 17426588
Volume :
1378
Database :
OpenAIRE
Journal :
Journal of Physics: Conference Series
Accession number :
edsair.doi...........396cd2bd0524f0f3e87d2e731cd234aa
Full Text :
https://doi.org/10.1088/1742-6596/1378/2/022025