A Mn(II) Metal-Organic Framework Constructed from a Tetrahedral Silicon-Cored Ligand

Authors :: Qingyu Ma
Rui Fang Guan
Deng Xu Wang
Guo Zhong Li
Source :: Applied Mechanics and Materials. :2367-2370
Publication Year :: 2013
Publisher :: Trans Tech Publications, Ltd., 2013.
Abstract: A novel metal-organic framework, MnCl2(BIPS)2•2CH3OH•2H2O (1) were synthesized from MnCl2 and a tetrahedral silicon-cored ligand, Me2Si(p-C6H4-imdazol-1-yl)2 (BIPS) under the slow diffusion method. The structure was determined by single-crystal X-ray diffraction. Complex 1 is a 2D sheet structure constructed from 1D chains with 34-atom metallamacrocycles.

Subjects :: Diffraction
Materials science
Silicon
Ligand
Diffusion
chemistry.chemical_element
General Medicine
chemistry.chemical_compound
Crystallography
chemistry
Tetrahedron
Sheet structure
Imidazole
Metal-organic framework

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