Coordination behaviour of ferrocenylthiosemicarbazone in a novel hetero trinuclear nickel(II) complex: Synthesis, spectral, electrochemistry and X-ray crystallography

The coordination behaviour of ferrocenylthiosemicarbazone was investigated in a trinuclear [Ni(Fctsc)2] complex. The structure of the complex has been studied by X-ray crystallography. The complex crystallizes in rhombohedral space group R 3 ¯ c with six molecules per unit cell has the dimensions of a = 28.8042(2) A, b = 28.8042(2) A and c = 19.5131(3) A, α = 90°, β = 90°, γ = 120°. The electronic communication between the metal centers has been studied by cyclic voltammetry.