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Buddledin C from Pulicaria prostrata and selective synthesis of its epoxy derivative

Authors :
T. T. Edil'baeva
Makhmut M. Shakirov
K. M. Turdybekov
D. T. Sadyrbekov
S. M. Adekenov
Yu. V. Gatilov
V. A. Raldugin
A. T. Kulyyasov
G. A. Atazhanova
Source :
Chemistry of Natural Compounds. 42:41-45
Publication Year :
2006
Publisher :
Springer Science and Business Media LLC, 2006.

Abstract

The structure of the sesquiterpene ketone buddledin C isolated from Pulicaria prostrata (Gilib.) Aschers., was confirmed by XSA. The stereochemistry of its epoxide, which was formed selectively by treating it with hydrogen peroxide in alkaline solution, was proposed based on quantum-chemical and molecular-mechanical calculations.

Details

ISSN :
15738388 and 00093130
Volume :
42
Database :
OpenAIRE
Journal :
Chemistry of Natural Compounds
Accession number :
edsair.doi...........3cbb253c656502ec816a1c3e65699f42
Full Text :
https://doi.org/10.1007/s10600-006-0032-7