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The g-C3N4 modified by AgBr and ZIF-8 adsorption-photocatalysis synergistic degradation of bisphenol A

Authors :
Kunjie Li
Wei Wu
Qi Meng
Shenyu Liao
Cong Shao
Wei Zheng
Zhenfei Jiang
Shanshan Feng
Yunjie Ge
Sheng Feng
Chunying Duan
Source :
Research on Chemical Intermediates. 47:1471-1487
Publication Year :
2021
Publisher :
Springer Science and Business Media LLC, 2021.

Abstract

In this work, a ternary complex (g-C3N4/ZIF-8/AgBr) was prepared by modifying the surface of the protonated graphitic carbon nitride (g-C3N4) with photosensitive AgBr and zeolitic imidazolate framework-8 (ZIF-8), and its physicochemical parameters, crystal morphology and electrochemical properties were characterized using a series of techniques. The modified g-C3N4 not only improves the ability to capture pollutants in water, but also efficiently catalyzes the degradation of bisphenol A (BPA) in water by rapidly producing superoxide radicals (·O2− ), cavitation (h+) and hydroxyl radicals (·OH) in visible light, with the removal efficiency reaching 80.4%. The activity of catalytic degradation of BPA from strong to weak is g-C3N4/ZIF-8/AgBr, g-C3N4/AgBr, g-C3N4/ZIF-8, AgBr, g-C3N4, ZIF-8. After four cycles of experiments, it was found that g-C3N4/ZIF-8/AgBr had still considerable degradation ability (70.2%) and stability.

Details

ISSN :
15685675 and 09226168
Volume :
47
Database :
OpenAIRE
Journal :
Research on Chemical Intermediates
Accession number :
edsair.doi...........3d21a7ec3f02ff6b6e28b7c3671e001a