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Reformulation of quartic centrifugal distortion Hamiltonian
- Source :
- Journal of Molecular Spectroscopy. 53:246-249
- Publication Year :
- 1974
- Publisher :
- Elsevier BV, 1974.
-
Abstract
- Some of Watson's quartic centrifugal distortion parameters have the undesirable property that they become infinite when two rotational constants are equal. A proposal is made for a redefinition of the parameters in such a way that they stay well defined in the symmetric top limit.
Details
- ISSN :
- 00222852
- Volume :
- 53
- Database :
- OpenAIRE
- Journal :
- Journal of Molecular Spectroscopy
- Accession number :
- edsair.doi...........3ff62a77d70699864677b8626eb3d8f3
- Full Text :
- https://doi.org/10.1016/0022-2852(74)90129-5