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Reformulation of quartic centrifugal distortion Hamiltonian

Authors :
B.P. van Eijck
Source :
Journal of Molecular Spectroscopy. 53:246-249
Publication Year :
1974
Publisher :
Elsevier BV, 1974.

Abstract

Some of Watson's quartic centrifugal distortion parameters have the undesirable property that they become infinite when two rotational constants are equal. A proposal is made for a redefinition of the parameters in such a way that they stay well defined in the symmetric top limit.

Details

ISSN :
00222852
Volume :
53
Database :
OpenAIRE
Journal :
Journal of Molecular Spectroscopy
Accession number :
edsair.doi...........3ff62a77d70699864677b8626eb3d8f3
Full Text :
https://doi.org/10.1016/0022-2852(74)90129-5