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Template-assisted preparation of Au nanowires and their application in nitrite ions sensing

Authors :
Yan Zhang
Zhiquan Cai
Min Zhang
Faliang Cheng
Peng Liu
Meiqiong Chen
Source :
Journal of Electroanalytical Chemistry. 773:1-6
Publication Year :
2016
Publisher :
Elsevier BV, 2016.

Abstract

Au nanowires synthesized via a template-assisted method using Te nanowires as templates are selected as electrode materials for detecting nitrite ions. The result is verified through a series of electrochemical measurements to demonstrate that Au nanowire-modified electrodes exhibit high catalytic activity for nitrite ions. Au nanowire-modified electrodes with a loading of 0.006 μg/mm2 achieve a relatively high catalytic current oxidation with a potential of + 0.83 V. The proposed sensor exhibits a rapid response to nitrite ions (less than 5 s), and the oxidation current shows a linear relationship (R = 0.9982) with the nitrite ions concentration ranging from 1 μM to 0.97 mM, at a detection limit of 0.2 μM (S/N = 3). The proposed sensor also demonstrates high sensitivity and excellent selectivity. This study emphasizes on the practicality of the proposed sensor in the measurement of nitrite ions in tap water and pickled food.

Details

ISSN :
15726657
Volume :
773
Database :
OpenAIRE
Journal :
Journal of Electroanalytical Chemistry
Accession number :
edsair.doi...........40db70f489ff93c6e64f9a6ed1ebaf3c
Full Text :
https://doi.org/10.1016/j.jelechem.2016.03.021