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Facile construction of the all-bridge-position-functionalized 2,4,6,8-tetraazaadamantane skeleton and conversion of its N-functionalities

Authors :
Rongbin Cai
Qi Zhou
Tianjiao Hou
Bing Li
Yunzhi Liu
Huan Li
Yuan Gao
Longyi Zhu
Jun Luo
Source :
Organic Chemistry Frontiers. 9:3684-3691
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

An unusual protocol of a “one-pot” three-step strategy to build the 2,4,6,8-tetraazaadamantane skeleton was developed. 17 products were obtained in 19–46% yields, and the N-benzyl groups were transferred to nitroso, acetyl, benzoyl and nitro groups.

Subjects

Subjects :
Organic Chemistry

Details

ISSN :
20524129
Volume :
9
Database :
OpenAIRE
Journal :
Organic Chemistry Frontiers
Accession number :
edsair.doi...........41473a8252f7fe5c0bdbb050c67bac77
Full Text :
https://doi.org/10.1039/d2qo00427e