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Ultrasound assisted synthesis, characterization and electrochemical study of a tetradentate oxovanadium diazomethine complex
- Source :
- Journal of Molecular Structure. 1120:239-244
- Publication Year :
- 2016
- Publisher :
- Elsevier BV, 2016.
-
Abstract
- The oxovanadium (IV) complex “VOL” of a tetradentate Schiff base ligand derived from the condensation of diaminoethane and 2-hydroxy-1-naphthaldehyde was efficiently prepared via ultrasound irradiation and the template effect of VO(acac)2. The resulting product was characterized by elemental analysis, infrared, electronic absorption and molar conductance measurement. Single X-ray structure analysis showed that the complex is a monomeric five-coordinate with a distorted square pyramidal geometry. It crystallizes in monoclinic system having unit cell parameters a = 8.3960 (5) A; b = 12.5533 (8) A and c = 18.7804 (11) A; α = γ = 90°; β = 104.843°(2), with P 21/c space group. Cyclic voltammetry of the complex, carried out on a glassy carbon (GC) electrode in DMF, showed reversible cyclic voltammograms response in the potential range 0.15–0.60 V involving a single electron redox wave VV/VIV, the diffusion coefficient is determinedusing GC rotating disk electrode. The Levich plot Ilim = f(ω1/2), was used to calculate the diffusion-convection controlled currents.
- Subjects :
- Schiff base
010405 organic chemistry
Organic Chemistry
Analytical chemistry
Glassy carbon
010402 general chemistry
Electrochemistry
01 natural sciences
Square pyramidal molecular geometry
0104 chemical sciences
Analytical Chemistry
Inorganic Chemistry
chemistry.chemical_compound
chemistry
X-ray crystallography
Physical chemistry
Cyclic voltammetry
Rotating disk electrode
Spectroscopy
Monoclinic crystal system
Subjects
Details
- ISSN :
- 00222860
- Volume :
- 1120
- Database :
- OpenAIRE
- Journal :
- Journal of Molecular Structure
- Accession number :
- edsair.doi...........427cecfce77fbce8cc6ddb5b80fb73c3