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High-Frequency ESR Measurements of S = 1/2 1-D Heisenberg Antiferromagnetic Zig-Zag Chain (VO)(SO4)(2,2-bpy)
- Source :
- Applied Magnetic Resonance. 40:481-487
- Publication Year :
- 2011
- Publisher :
- Springer Science and Business Media LLC, 2011.
-
Abstract
- High-frequency electron spin resonance (ESR) measurements of S = 1/2 one-dimensional Heisenberg antiferromagnetic zig-zag chain substance (VO)(SO4)(2,2-bpy) were performed in the temperature region from 1.8 to 265 K. ESR measurements at 265 K show typical powder pattern spectra of the V4+ ion and g || = 1.925 ± 0.001 and g ⊥ = 1.976 ± 0.001 were obtained. Although the magnetic susceptibility shows a maximum at 3.1 K suggesting the existence of a short-range order, no g-shift and line width broadening were observed down to 1.8 K. We suggest that these temperature-independent features of ESR can be attributed to the result of frustration in (VO)(SO4)(2,2-bpy).
- Subjects :
- Quantum phase transition
Solid-state physics
Condensed matter physics
Chemistry
media_common.quotation_subject
Frustration
Magnetic susceptibility
Atomic and Molecular Physics, and Optics
Spectral line
law.invention
Ion
Crystallography
law
Antiferromagnetism
Electron paramagnetic resonance
media_common
Subjects
Details
- ISSN :
- 16137507 and 09379347
- Volume :
- 40
- Database :
- OpenAIRE
- Journal :
- Applied Magnetic Resonance
- Accession number :
- edsair.doi...........44629fb301bd3c2575bc0f3573709669