Structural Relaxation of Pd 39 Ni 10 Cu 30 P 21 Bulk Metallic Glass Under High Pressure

The Pd39Ni10Cu30P21 bulk metallic glass is isothermally relaxed under various pressures. The degree of the structural relaxation is evaluated in terms of the enthalpy recovery behaviours involved in the irreversible glass transition processes by using a temperature-modulated differential scanning calorimetry technique. A roughly Linear increase of the recovery enthalpy is observed within the experimental pressure range fi-om 2.67 to 4.45 GPa, which reflects the release of the frozen-in enthalpy in the as-quenched glass with increasing relaxation pressure. The pressure dependence of the timescale of the enthalpy recovery processes is also exhibited.