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Phosphine–borane derivatives. Part VII. The vibrational spectra of the phosphine adducts of boron trihalides
- Source :
- J. Chem. Soc., Dalton Trans.. :595-603
- Publication Year :
- 1974
- Publisher :
- Royal Society of Chemistry (RSC), 1974.
-
Abstract
- The i.r. and Raman spectra of PH3,BCl3, PD3,BCl3, PH3,BBr3, PD3,BBr3, PH3,BI3, and PD3,BI3 are reported. A normal co-ordinate analysis, utilizing a modified Urey–Bradley force field, confirms the assignments. All the adducts give best fits for a HPH angle of ca. 105–106°.
Details
- ISSN :
- 13645447 and 03009246
- Database :
- OpenAIRE
- Journal :
- J. Chem. Soc., Dalton Trans.
- Accession number :
- edsair.doi...........47e8cc21227ea6b8e5af4783db8df2b3