1,3-Dipolar Cycloaddition of Nitrones to a Nitrile Functionality in closo-Decaborate Clusters: A Novel Reactivity Mode for the Borylated C≡N Group

Authors :: Leonid A. Lisitsyn
Nadezhda A. Bokach
Konstantin Yu. Zhizhin
Aleksey L. Mindich
Fedor M. Dolgushin
Matti Haukka
Nikolay T. Kuznetsov
Vadim Yu. Kukushkin
Serguei A. Miltsov
Andrey P. Zhdanov
Source :: Organometallics. 31:1716-1724
Publication Year :: 2012
Publisher :: American Chemical Society (ACS), 2012.
Abstract: The Z-configured nitrones –O+N(Me)═C(H)C6H4R2-p (R2 = OMe (2a), Me (2b), NO2 (2c)) react with the nitrile functionality of the closo-decaborate clusters [Bun4N][B10H9(NCR1)] (R1 = Me (1a), Et (1b),...

Subjects :: Inorganic Chemistry
chemistry.chemical_compound
Nitrile
Stereochemistry
Chemistry
Organic Chemistry
1,3-Dipolar cycloaddition
Reactivity (chemistry)
Physical and Theoretical Chemistry

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