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Oxidative transformations of diisobornyl disulfide

Authors :
A. N. Aryku
Pavel F. Vlad
E. S. Sekara
Alic Barba
Ion Dragalin
K. I. Kuchkova
Nicon Ungur
Source :
Russian Chemical Bulletin. 63:2074-2076
Publication Year :
2014
Publisher :
Springer Science and Business Media LLC, 2014.

Abstract

13-Amino-14,15-dinorlabd-8(9)-ene was synthesized from sclareol in four steps in 47% total yield. 14,15-Dinorlabd-8(9)-en-13-one was an intermediate compound, reduction of its oxime with LiAlH4 was a key step of this synthetic scheme.

Subjects

Subjects :
chemistry.chemical_compound
Chemistry
Sclareol
Stereochemistry
Yield (chemistry)
Sclareol oxide
Disulfide bond
Organic chemistry
General Chemistry
Oxidative phosphorylation
Oxime

Details

ISSN :
15739171 and 10665285
Volume :
63
Database :
OpenAIRE
Journal :
Russian Chemical Bulletin
Accession number :
edsair.doi...........48de06af4f9077b843e7587b03bb9ae5
Full Text :
https://doi.org/10.1007/s11172-014-0703-7
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