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A Facile One-Step Synthesis of Ethyl 2-(L,L-Dialkyl and Arylmethyl) Malonates
- Source :
- Synthetic Communications. 29:343-350
- Publication Year :
- 1999
- Publisher :
- Informa UK Limited, 1999.
-
Abstract
- Diethyl ethoxymethylenemalonate (EMME) is unexpectedly converted into diethyl 2-(1,1 -dialkyl and diarylmethyl) malonate derivatives by a classical Grignard reaction. Addition of organocuprates to EMME gave diethyl 2-(l-ethoxyalkyl) malonate derivatives. The yields range from 42-63%.
Details
- ISSN :
- 15322432 and 00397911
- Volume :
- 29
- Database :
- OpenAIRE
- Journal :
- Synthetic Communications
- Accession number :
- edsair.doi...........49d06e4c9b657dc9f23b03d8385350bd
- Full Text :
- https://doi.org/10.1080/00397919908085773