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Electrochemical degradation of acid orange II dye using mixed metal oxide anode: Role of supporting electrolytes

Authors :
Jingyu Wu
Chunyong Zhang
Xiaoming Du
Degang Fu
Zhenzhu He
Source :
Journal of the Taiwan Institute of Chemical Engineers. 59:303-310
Publication Year :
2016
Publisher :
Elsevier BV, 2016.

Abstract

Here, the electrochemical degradation of 50 mg/dm 3 Acid Orange II dye over mixed metal oxide anode has been conducted in the presence of different supporting electrolytes (sulfate, chloride, and their mixture of different proportion). A factorial design methodology was adopted to evaluate the statistically important input variables, among treatment time (30–60 min), flow rate (300–600 ml/min), applied current density (2.58–5.16 mA/cm 2 ) and total concentration of supporting electrolytes (1.0–4.0 mM), on degradation performance; the latter was assessed in terms of color removal rate. The results obtained, demonstrated that the electrolytic oxidation was strongly favored by the presence of chlorides. In addition, the information obtained from electrochemical measurements and UV–vis spectra were used to better clarify the different roles of operating parameters recorded.

Details

ISSN :
18761070
Volume :
59
Database :
OpenAIRE
Journal :
Journal of the Taiwan Institute of Chemical Engineers
Accession number :
edsair.doi...........4c470fc90524e0ea6cfde3740297867b