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Low-Temperature Anomalies in Strong and Fragile Glass Formers

Authors :
Roberto Calemczuk
B. Salce
Eugène Duval
D. Quitmann
Alexander Kisliuk
Alexei P. Sokolov
Source :
Physical Review Letters. 78:2405-2408
Publication Year :
1997
Publisher :
American Physical Society (APS), 1997.

Abstract

The low-temperature anomalies of glass forming systems are analyzed focusing on the concept of fragility. It is shown that two extremes on the fragility plot, Si${\mathrm{O}}_{2}$ and C${\mathrm{a}}_{0.4}$${\mathrm{K}}_{0.6}$(N${\mathrm{O}}_{3}$${)}_{1.4}$, show a strong difference in specific heat in the range of excess vibrational contribution. This difference cannot be explained in the framework of the soft potential model in its present state. A relation between the excess vibrational contribution and the amount of structural fluctuations is suggested. It is shown that the suggested relation explains the found difference in low-temperature specific heat between strong and fragile glass formers.

Details

ISSN :
10797114 and 00319007
Volume :
78
Database :
OpenAIRE
Journal :
Physical Review Letters
Accession number :
edsair.doi...........4e2b4e29cb2c80ac86eec9493be3df57
Full Text :
https://doi.org/10.1103/physrevlett.78.2405