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Composition of Hydrocarbons in Synthetic Diamonds Grown in a Fe—Ni—C System (according to Gas Chromatography—Mass Spectrometry Data)

Authors :
N. P. Pokhilenko
V. M. Sonin
T. A. Bul’bak
A. I. Chepurov
Anatoly A. Tomilenko
Egor Zhimulev
Source :
Doklady Earth Sciences. 481:1004-1007
Publication Year :
2018
Publisher :
Pleiades Publishing Ltd, 2018.

Abstract

The first data of chromatography—mass spectrometry analysis of volatiles from crystals of synthetic diamonds grown in a Fe—Ni—C system at 1350–1400°С and 5.5–6.0 GPa are presented. The composition of the fluid in equilibrium with the metal-carbon melt is determined, and a comparative estimation for the compounds of different hydrocarbons and their derivatives is made. It is shown that a significant role in these processes is played by high-molecular-weight hydrocarbons; and the total share of hydrocarbons and their derivatives in the fluid compounds can exceed 86%.

Details

ISSN :
15318354 and 1028334X
Volume :
481
Database :
OpenAIRE
Journal :
Doklady Earth Sciences
Accession number :
edsair.doi...........4e48b2ff5a2a50e6bfb9e47f827a1442
Full Text :
https://doi.org/10.1134/s1028334x18080111