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Selective oxidation of glycerol to lactic acid under acidic conditions using AuPd/TiO2 catalyst

Authors :
Yanbin Li
Zhimin Liu
Jilei Xu
Bo Yu
Hongye Zhang
Yanfei Zhao
Leiduan Hao
Sha Chen
Source :
Green Chemistry. 15:1520
Publication Year :
2013
Publisher :
Royal Society of Chemistry (RSC), 2013.

Abstract

The selective oxidation of glycerol was investigated using AuPd/TiO2 as the catalyst in the presence of AlCl3, and lactic acid was obtained as the predominant product. It was demonstrated that AuPd/TiO2 and AlCl3 played synergistic roles in the production of lactic acid. The possible reaction pathway was proposed, in which glycerol was first oxidized to glyceraldehyde and dihydroxyacetone, catalysed by AuPd/TiO2, followed by the formation of lactic acid, catalyzed by AlCl3.

Details

ISSN :
14639270 and 14639262
Volume :
15
Database :
OpenAIRE
Journal :
Green Chemistry
Accession number :
edsair.doi...........5095b791c07e22f55f924378827f7e82
Full Text :
https://doi.org/10.1039/c3gc40314a