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Synthesis and crystal structure of the double barium–titanium isopropoxide [Ba4Ti4(µ4-O)4(µ3-OR)2(µ-OR)8(OR)6(ROH)4][Ba4Ti4(µ4-O)4(µ3-OR)2(µ-OR)9(OR)5(ROH)3]

Authors :
Nataliya Ya. Turova
M. I. Yanovskaya
Yuri T. Struchkov
Victoriya K. Limar
Vadim G. Kessler
Alexander I. Yanovsky
Source :
J. Chem. Soc., Chem. Commun.. :1605-1606
Publication Year :
1991
Publisher :
Royal Society of Chemistry (RSC), 1991.

Abstract

An X-ray structural study of the crystals isolated from the solutions obtained by the reaction of Ba metal with Ti(OPri)4 in isopropyl alcohol has been carried out; the crystals of the compound, which is a precursor for the synthesis of BaTiO3, contain molecules of two different kinds [Ba4Ti4O4(OR)16(ROH)4] and [Ba4Ti4O4(OR)16(ROH)3], where R = Pri.

Details

ISSN :
00224936
Database :
OpenAIRE
Journal :
J. Chem. Soc., Chem. Commun.
Accession number :
edsair.doi...........50c4618f9d3993d877ef6385a7728c68
Full Text :
https://doi.org/10.1039/c39910001605