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Novel sign-alternation rule for the triplet state in aromatic systems

Authors :
Yoshiya Kanda
Yasuhiko Gondo
Source :
International Journal of Quantum Chemistry. 18:185-188
Publication Year :
1980
Publisher :
Wiley, 1980.

Abstract

Within the framework of the LCAO-MO theory, a novel sign-alternation rule has been found empirically for the lowest excited ππ* triplet state in the alternant aromatic system. This rule can be applied to identify the phosphorescent state.

Details

ISSN :
1097461X and 00207608
Volume :
18
Database :
OpenAIRE
Journal :
International Journal of Quantum Chemistry
Accession number :
edsair.doi...........50e8e0c4b307ec4dd5400f82a011a1cf
Full Text :
https://doi.org/10.1002/qua.560180125