A fungal fusicoccane with ophiobolane-type functionalities: structure determination by n.m.r. spectroscopy aided by biosynthetic incorporation of [1,2-13C2]acetate

Authors :: J. B. Stothers
R. C. Zimmer
Albert Stoessl
Source :: Journal of the Chemical Society, Chemical Communications. :508
Publication Year :: 1987
Publisher :: Royal Society of Chemistry (RSC), 1987.
Abstract: The structure of a diterpene aldehyde isolated from a fungus provisionally identified as Cercospora traversiana Saccardo was elucidated as (1) mainly by extensive 1H and 13C n.m.r. studies and confirmed by the labelling patterns of the substance enriched with [1,2-13C2]acetate.

Subjects :: chemistry.chemical_classification
biology
Stereochemistry
Fungus
Fungi imperfecti
biology.organism_classification
Aldehyde
chemistry.chemical_compound
chemistry
Cercospora
Labelling
Molecular Medicine
Diterpene
Spectroscopy

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